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Cas no 7664-39-3 Hydrogen fluoride (no water) chemical formula HF high purity Inorganic compound 99.9% Inorganic acid

Hydrogen fluoride (fluorane) is an inorganic compound with chemical formula HF. It is a very poisonous, colorless gas or liquid that dissolves in water to yield an aqueous solution termed hydrofluoric acid.

It is the principal industrial source of fluorine, often in the form of hydrofluoric acid, and is an important feedstock in the preparation of many important compounds including pharmaceuticals and polymers, e.g. polytetrafluoroethylene (PTFE).

HF is also widely used in the petrochemical industry as a component of superacids. Due to strong and extensive hydrogen bonding, it boils at near room temperature, much higher than other hydrogen halides.

Hydrogen fluoride is an extremely dangerous gas, forming corrosive and penetrating hydrofluoric acid upon contact with moisture. The gas can also cause blindness by rapid destruction of the corneas.

Hydrogen fluoride info:

Names
Other names
Fluorane
Identifiers
ChemSpider
KEGG
PubChem CID
RTECS number
  • MW7875000
Properties
HF
Molar mass 20.006 g·mol−1
Appearance colourless gas or colourless liquid (below 19.5 °C)
Odor unpleasant
Density 1.15 g/L, gas (25 °C)
0.99 g/mL, liquid (19.5 °C)
1.663 g/mL, solid (–125 °C)
Melting point −83.6 °C (−118.5 °F; 189.6 K)
Boiling point 19.5 °C (67.1 °F; 292.6 K)
completely miscible (liquid)
Vapor pressure 783 mmHg (20 °C)[1]
Acidity (pKa) 3.17 (in water),

15 (in DMSO) [2]

Conjugate acid Fluoronium
Conjugate base Fluoride
1.00001
Structure
Linear
1.86 D
Thermochemistry
Std molar
entropy
 (S298)
8.687 J/g K (gas)
−13.66 kJ/g (gas)
−14.99 kJ/g (liquid)
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